Brechin
Jornada 2
| 21 Sep 66 |  Aberdeen |
3 - 0 |  Greenock |
... |
| 21 Sep 66 |  Airdrieonia |
5 - 1 |  Montrose |
... |
| 21 Sep 66 |  Dunfermline |
1 - 3 |  Celtic |
... |
| 21 Sep 66 |  Rangers FC |
3 - 0 |  Ayr United |
... |
| 14 Sep 66 | Ayr United |
1 - 1 | Rangers FC |
... |
| 14 Sep 66 | Celtic |
6 - 3 | Dunfermline |
... |
| 14 Sep 66 | Montrose |
3 - 3 | Airdrieonia |
... |
| 14 Sep 66 | Greenock |
3 - 1 | Aberdeen |
... |
Jornada 3
| 24 Oct 66 | Rangers FC |
2 - 0 | Aberdeen |
... |
| 19 Oct 66 | Rangers FC |
2 - 2 | Aberdeen |
... |
| 17 Oct 66 | Celtic |
2 - 0 | Airdrieonia |
... |
Jornada 4
| 29 Oct 66 | Rangers FC |
0 - 1 | Celtic |
... |
Aberdeen
Airdrieonians
Celtic
Dundee
Dundee United
Falkirk
Heart of Midlothian
Hibernian FC
Kilmarnock
Motherwell
Partick Thistle
Rangers FC
St. Mirren
Clyde
Greenock Morton
St. Johnstone
Dunfermline Athletic FC
Hamilton Academical
Ayr United
Raith Rovers
Dumbarton
Queen of the South
East Fife
Arbroath
Queen's Park
Alloa Athletic
Stirling Albion
Cowdenbeath
Albion Rovers
Stenhousemuir
Forfar Athletic
Brechin City
Stranraer
Montrose
Berwick Rangers
East Stirlingshire
Third Lanark
Clydebank